Adiponitrile

    • Product Name: Adiponitrile
    • Chemical Name (IUPAC): hexanedinitrile
    • CAS No.: 111-69-3
    • Chemical Formula: C6H8N2
    • Form/Physical State: Liquid
    • Factroy Site: No.1788, Development Road, Ruian Economic Development Zone, Ruian, Wenzhou, Zhejiang
    • Price Inquiry: sales3@ascent-chem.com
    • Manufacturer: Huafon Group Co., Ltd
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    Specifications

    HS Code

    488432

    Chemical Name Adiponitrile
    Cas Number 111-69-3
    Molecular Formula C6H8N2
    Molar Mass 108.14 g/mol
    Appearance Colorless to pale yellow liquid
    Odor Faint, sweet odor
    Melting Point -2 °C
    Boiling Point 295 °C
    Density 0.96 g/cm³ at 20 °C
    Solubility In Water Slightly soluble
    Flash Point 127 °C
    Refractive Index 1.446 at 20 °C
    Vapor Pressure 0.01 mmHg at 20 °C
    Autoignition Temperature 432 °C
    Pubchem Cid 8098

    As an accredited Adiponitrile factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Adiponitrile is packaged in a 200-liter blue UN-approved steel drum, sealed tightly, and labeled with hazardous chemical warnings.
    Container Loading (20′ FCL) Container Loading (20′ FCL) for Adiponitrile typically involves 80–100 drums or 16–20 metric tons, securely packed for safe transport.
    Shipping Adiponitrile is shipped as a hazardous material, usually in steel drums, tank trucks, or railcars. It must be properly labeled and handled with care due to its flammability and toxicity. Shipping requires compliance with relevant regulations, such as DOT and IMDG, ensuring proper ventilation, spill prevention, and protective packaging.
    Storage Adiponitrile should be stored in a cool, dry, and well-ventilated area, away from heat, sparks, open flames, and strong oxidizing agents. Containers must be tightly closed and clearly labeled. Use approved, corrosion-resistant containers. Adiponitrile is sensitive to moisture; avoid exposure to water. Ensure proper spill containment and have safety measures in place to handle potential leaks or exposure.
    Shelf Life Adiponitrile typically has a shelf life of 2 years when stored in tightly closed containers, away from heat, moisture, and light.
    Application of Adiponitrile

    Applications of Adiponitrile in Industrial Manufacturing

    As a direct manufacturer of adiponitrile, we provide a core intermediate essential to the synthesis of nylon 6,6 and related specialty chemicals. Our product integrates into multiple established industrial sectors, each governed by demanding compliance systems and tailored production practices. Below are key application segments where adiponitrile underpins advanced chemical processes and end-product quality.

    1. Nylon 6,6 Polymer Production

    Nylon 6,6 manufacturing relies on adiponitrile as its principal precursor for generating hexamethylenediamine, which subsequently reacts with adipic acid. We supply adiponitrile to plants with large-scale continuous polymerization lines, where real-time purity monitoring directly impacts polymer molecular weight, color stability, and fiber-spinning consistency. Producers typically require trace impurity control to meet technical textile and engineering plastics specifications, as any deviation from formulation parameters leads to off-grade chips or extrudates. Our facility supports downstream partners by offering logistics and technical support that meet precise production windows and tank-level replenishment cycles.

    Industry compliance standards

    • ISO 9001:2015 (Quality Management Systems for Chemical Manufacturing)
    • OEKO-TEX® Standard 100 (Textile Inputs Safety, for apparel nylon fibers)
    • REACH (EU Regulation EC 1907/2006 – Registration and use of substances in polymers)
    • US EPA TSCA (Reporting requirements for chemical intermediates in polymer production)

    Typical usage ratio

    • 1.00-1.05 molar equivalents per mol of adipic acid; ratio may adjust for targeted molecular weight and viscosity index requirements

    Downstream process integration

    • Hydrogenation of adiponitrile to hexamethylenediamine (HMDA) via catalytic reactors; subsequent salt formation and polymerization in batch or continuous reactors

    Final product types

    • Nylon 6,6 chips
    • Technical yarns and industrial filaments (tire cord, airbags)
    • Engineering-grade injection molded resins
    • Monofilaments for brush and industrial textile applications

    2. Specialty Polyamide Resin Synthesis

    In advanced polyamide resin plants, adiponitrile enables synthesis routes for copolyamides designed for films and coatings which require tailored melting points, toughness, and chemical resistance. Producers formulated blends using adiponitrile-derived hexamethylenediamine and selected dicarboxylic acids to achieve precise monomer ratios. These copolymers demand strict monomer conversion rates and impurity tracking, particularly for aerospace and automotive-grade films. We maintain lot traceability and standardized purity specifications, facilitating repeatable performance in downstream compounding and extrusion operations.

    Industry compliance standards

    • IATF 16949 (Automotive Quality System Standard)
    • ISO 2230 (Plastics — Safe Processing Guidelines)
    • UL Yellow Card (for polymer flammability and composition in end-use films)
    • EU RoHS Directive (Restriction of Hazardous Substances in electronic applications)

    Typical usage ratio

    • Varies with copolymer design: 0.30–0.95 molar equivalent of adiponitrile-derived diamine per monomer batch; adjusted based on targeted copolymer architecture

    Downstream process integration

    • Monomer stream blending and batch polymerization in sealed reactors, followed by extrusion, annealing, and film/sheet calendering lines

    Final product types

    • High-performance polyamide copolymer films
    • Coextruded packaging foils for electronics
    • Coatings for automotive wire harness binders
    • Hot-melt adhesives for industrial assembly

    3. Synthesis of Hexamethylenediamine-Based Chemical Intermediates

    Adiponitrile hydrogenation serves as an upstream step for producing specialty hexamethylenediamine derivatives. Downstream chemical plants utilize these derivatives for manufacturing chain extenders in polyurethane systems, crosslinkers for epoxy-resin formulations, and modifiers in high-performance coatings. Stringent moisture and trace cyanide level management are standard to avoid side reactions in subsequent catalytic steps. To support these high-purity demands, we control batch records and maintain logistics cycles tailored to batch and continuous hydrogenation reactors.

    Industry compliance standards

    • ISO 14001 (Environmental Systems: Control of Volatile Organic Compound Emissions)
    • GHS-CLP (EU Classification, Labelling and Packaging for chemical intermediates)
    • Responsible Care® (Voluntary chemical safety management standards)
    • US OSHA 29 CFR 1910.119 (Process Safety Management of Highly Hazardous Chemicals)

    Typical usage ratio

    • Yields from 70–98% conversion (1.00:1 stoichiometric input), optimized per hydrogenation catalyst system and desired mono- or bifunctional output

    Downstream process integration

    • Feedstock injection into high-pressure fixed-bed or slurry-phase hydrogenation reactors; subsequent purification and blending for intermediate formulation

    Final product types

    • Hexamethylenediamine dihydrochloride
    • Chain extenders for polyurethane elastomer casting
    • Amine-based crosslinking agents for powder coatings
    • Surface-cured resins and construction adhesives

    4. High-Performance Solvent and Electrolyte Additive Manufacturing

    Adiponitrile receives use as a key solvent precursor and functional additive for lithium battery electrolyte formulations. Producers require stringent electrical conductivity, low moisture content, and defined boiling point profiles to achieve reliable low-temperature performance in battery systems for electric vehicles and stationary energy storage units. Our process enables downstream partners to blend precise proportions of nitrile-based additives, ensuring safe and consistent cell assembly while meeting international battery quality certification protocols.

    Industry compliance standards

    • IEC 62660-2:2018 (Safety requirements for lithium-ion battery cells produced with specialty electrolyte blends)
    • GB/T 31467.3 (Test Procedures for Electric Vehicle Power Battery Systems in China)
    • ISO 18300 (Safety and performance for organic solvents in electronics and batteries)
    • UN Manual of Tests and Criteria, Part III, Section 38.3 (Lithium Battery Safety Testing)

    Typical usage ratio

    • 2–10% by weight as a blend component with organic carbonates; precise proportion varies according to the targeted conductivity, viscosity, and performance window

    Downstream process integration

    • Direct metering and mixing within battery-grade cleanroom electrolyte reactors; followed by vacuum drying, particle filtration, and incorporation into cell filling processes

    Final product types

    • Non-aqueous electrolyte blends for lithium-ion batteries
    • Solvent formulations for specialty capacitors
    • Conductivity enhancers in next-generation battery modules
    • Precursor components in cooling or dielectric fluids for electronics

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    Certification & Compliance
    More Introduction

    Adiponitrile: Supporting Chemical Progress with Consistent Quality

    What Real Manufacturing Looks Like with Adiponitrile

    Adiponitrile isn't just a name in our catalog – it represents years of refining and scaling a process where reliability makes all the difference. Out on the production line, there’s a clear difference between materials made for traders’ shelves and batches crafted with downstream customers in mind. Our team focuses on what works in actual industrial settings, building on day-in, day-out feedback from operators who turn raw materials into practical goods.

    Our latest Adiponitrile model, produced via the electrohydrodimerization of acrylonitrile, reflects this backbone of practical field expertise. This method gives us tight control over process impurities, so every drum stays within the required 99.9% purity – measured at the tank, not guessed from a spreadsheet. Low water and amine content reduce risk of side reactions that tie up equipment or undermine yields. We monitor color, nitrogen content, and acidity as non-negotiable indicators of a clean run.

    Understanding Adiponitrile’s Impact on Manufacturing

    For those of us who wear lab coats as often as safety boots, Adiponitrile isn’t some abstract mid-stream chemical. It forms the core of efficient hexamethylenediamine production. This material, in turn, means manufacturers get consistent, high-molecular-weight Nylon 66 out of their reactors. Nylon 66 wouldn’t exist in its current high-performance forms without reliable Adiponitrile behind it. Poor batch quality leads to variability in end-polymer chain length – causing fabric defects, reduced fiber strength, and a whole set of plant headaches where scrap piles up.

    Surface-level specifications posted by resellers rarely reflect what actually happens in reactors. We have dealt with the consequences of trace chlorides, water above 30 ppm, or unstable color indices that drift over storage time. In our experience, only tight process management and constant operator checks can hold these variables in line. A spec sheet printed on glossy paper never protects a line against a bad feedstock. Long-term customers often point to batch repeatability as the main reason they stick with us, even if a competitor sometimes dangles lower prices.

    Why Production Matters Beyond the Lab Scale

    Scaling Adiponitrile output isn’t just about technical bravado. To support customers making thousands of tons of polyamide, we need scalability that doesn’t break down under heat load, process fouling, or equipment stress. More than once we’ve seen pilot-scale engineers move to full production and discover that lab-purified Adiponitrile doesn’t hold up when tank trucks sit through summer rail delays or cross-continental shipping. The actual trace metal profile and organic carryover can wreck catalyst beds if unchecked, or catalyze side product formation that never showed up under sterile conditions.

    We adopted a multi-stage distillation step after a client in Southeast Asia reported yellowing in finished yarn due to minute iron carryover from a supplier’s stainless steel lines. We trace each drum back to the exact process batch and distillation run, using online analyzers and old-fashioned grab samples. If a problem shows up on the customer’s end, we can pinpoint exactly what changed on our side, and fix it in the next cycle.

    In production work, time matters just as much as chemistry. Waiting for a late chemical shipment while workers stand idle means pressure from every side. We keep on-site stock of Adiponitrile to cover tight turnarounds, especially during seasonal demand spikes for engineering plastics or automotive supply chains. Building enough redundancy into logistics only happens after witnessing, more than once, the domino effect of a missed truck shutting down a multi-million-dollar line.

    Choosing Adiponitrile: More than Just Grade and Purity

    Not all Adiponitrile is the same. The differences can hide in stability during long-term storage, compatibility with stainless or glass-lined tanks, and whether the monomer supports desired polymer chain propagation in Nylon 66 lines. We found that nitrogen and acidity specs impact how diaminononane and other by-products build up. Only hands-on batch tracking shows whether an additive or small impurity is the root cause of a customer’s unexpected problems.

    By sticking to a consistent raw material supplier for acrylonitrile and running regular checks for peroxide content, we have pushed down variability to a level where even sensitive HPLC methods pick up very little run-to-run noise. Our Adiponitrile features a colorless, low-odor, low-acid profile, which not only supports frontline polymerization but keeps downstream equipment cleaning cycles minimal.

    Many requests come from engineering plastics firms trying to move to lighter, tougher products for automotive or electronics. They notice quality differences not in the first run, but after weeks of operation – things like residue on reactor walls, or shifts in moisture pickup rates in finished plastics. Real expertise means talking to operators who have tackled these kinds of headaches, and working together to adjust our Adiponitrile supply for long-term equipment health as well as product properties.

    Our Technical Support: Direct Problem Solving, Not Checklists

    Getting Adiponitrile into customers’ plants is just the start of a relationship. We approach technical support as hands-on troubleshooting – not checking off customer service forms. If an issue comes up during line startup or when product specs drift, we send engineers who know the plant environment. They work with on-site chemists to trace the link between specific feed impurities and downstream product issues. Customers benefit from the factory perspective: if a pump cavitation issue kicks off contamination, or if a seemingly minor pipe modification changes trace impurity carryover, we get to the root of it with the tools and experience learned from our own process improvements.

    Supply-chain teams know us as much for crisis management as for routine delivery. We’ve rerouted rail tankers across borders, arranged emergency nitrogen blanket shipments when a competitor’s Adiponitrile failed mid-run, and even stepped in as emergency supplier during flooding disruptions. Working at this scale sharpens risk awareness: real support isn’t measured in average-case delivery, but in how we keep production stable even under abnormal stress.

    Environmental Commitment and Process Safety

    Large-scale Adiponitrile manufacture brings with it a real environmental and safety responsibility. Our team has dealt with everything from accidental emissions to community complaints over odor. We run closed-loop vent gas treatment and modern water purification to cut plant releases far below regulatory thresholds – not because of a checklist, but to maintain a safe environment for the communities living near our operations. Frequent process audits keep equipment corrosion, vapor leaks, and storage risks in check.

    We use real-world process feedback to improve safety controls. Several years ago, a near-miss involving a pressure relief valve led us to redesign venting systems on our Adiponitrile tanks. Since then, on-site safety teams have held regular emergency drills, involving both operators and local response agencies. Being a manufacturer, not just a trading office, means our own staff share the same environment as local residents – so we take these responsibilities seriously.

    Innovating with Sustainable Feed and Process Improvements

    While Adiponitrile itself hasn’t changed much as a molecule, the way we manufacture it continues to evolve. We invest in catalyst development and green chemistry, including efforts to minimize by-products and cut down energy consumption per ton produced. Recent tests using renewable electricity in electrohydrodimerization have started to show promise, with pilot modules reducing overall energy load by several percent compared to grid-only power.

    Efficient waste heat recovery from the process lets us pre-heat solvents and cut down on fuel use in auxiliary boilers. In coordination with regional industrial parks, we route off-gases into local cogeneration plants for use as supplemental fuel, closing energy loops that were once a loss. These investments don’t just meet environmental targets – they also prevent the sudden regulatory disruptions that can cripple less-prepared producers and their downstream supply chains.

    For downstream users looking toward a circular economy, we’re running tests on partial bio-based feedstocks for acrylonitrile. While not yet fully commercial, early results point to moderate substitution possibilities without affecting reactivity or end-product properties. Staying close to the shop floor and testing at actual run scales helps us separate real progress from headline-driven fads.

    Practical Considerations in Handling and Storage

    Our field teams know that Adiponitrile is a tough customer outside controlled conditions. Its toxicity and volatility demand real respect in the plant. Over the years, we’ve worked with clients to modify unloading protocols, including nitrogen blanketing and double-sealed vapor capture for rail and road tankers. Strong odor thresholds and health concerns mean operators need robust training before any transfer job. We supply technical advisors and run joint reviews of storage tank design, focusing on minimum exposure, fast transfer rates, and material compatibility.

    Years spent mitigating condensation and water pickup in transport led us to switch to specialized tank coatings and pre-cleaning regimes for all our shipping containers. By recording transport times and evaluating thermal cycling effects, we improve tank cleaning and reduce risks of contamination or off-specification deliveries, especially in regions with hot or humid climates.

    Commercial Relationships Built on Long View, Not Quick Deals

    Having watched chemical cycles rise and fall, we know that price isn’t the only decision driver for buyers of Adiponitrile. Many of our longest-standing customers come back to us not on the basis of lowest cost, but reliability and openness in dealing with inevitable challenges. We sit down with supply chain managers and operations leaders to draw up run plans, seasonal buffer stocks, and alternate routing for emergencies – long before market shortages force the conversation.

    We value transparency regarding both process capability and limitations. If a surge in new orders risks longer lead times, we communicate that early, rather than promising the impossible and letting customers down. Over decades in the business, this mutual respect forms the backbone of both small specialty buyers and large-scale polyamide manufacturers trusting our team to make good on deliveries.

    How Our Adiponitrile Compares to Alternative Products

    Some producers pitch aliphatic dinitriles with looser specifications, hoping to catch spot demand or less technical buyers. Real users soon find that materials with less rigorous purification or relaxed impurity thresholds often lead to slower polymerization or frequent batch failures in high-throughput lines. Our experience tells us that plenty of “off-grade” or recycled Adiponitrile in the market shows erratic acid values, color drift, or unexpected reaction kinetics – all problems that quickly drive up costs through scrap and rework.

    We spend time in actual customer plants, evaluating not just on-paper claims but live process performance. By running side-by-side trials against generic equivalents, customers see firsthand which materials reduce downtime and deliver predictable mechanical properties in final products. For many large-volume clients, our tighter impurity control means less process adjustment, higher final yield, and lower cumulative plant maintenance. Reputational risk from supplying inconsistent Nylon 66 or related polyamines disappears when the chemical supply chain stays predictable.

    Unlike some alternates made by hydrocyanation, our route uses catalysts and electrolysis steps that minimize side dimer formation. For those targeting catalytic hydrogenation or downstream chemical synthesis, lower unsaturated by-products and temperature stability under pressurized conditions make downstream handling smoother. Some differences may only matter in demanding sectors, such as high-spec composites or advanced engineering resins, but those are often the difference between world-class performance and batch failures.

    Staying Grounded: Industry Networks and Continuous Improvement

    Working as a manufacturer means seeing up close how upstream decisions echo through to everyday production realities. We engage directly with chemical industry associations, research consortia, and regulatory bodies, not just to show compliance, but to stay tuned to coming changes or risks. Staff who’ve spent years in production bring insights to regulatory committees, from safe handling protocols to risk assessment of new feedstock sources, giving voice to practical, plant-level challenges.

    We set aside regular time for plant teams to share improvement ideas that don’t always show up in consultants’ reports. Some of our most important upgrades – from process heat integration to clever distillation modifications – came from these on-the-ground perspectives. Regular visits with leading academic laboratories give our team early looks at new catalysts, process intensification approaches, and digital monitoring; but implementation only happens after real-world validation in our own lines.

    No chemical supply can remain static if it wishes to serve evolving demands; our Adiponitrile evolves because our people are trained to listen to both the market and the machinery. By fostering a continuous-learning culture, we adapt to challenges – whether they come from new environmental rules, sudden demand spikes, or the subtle complexities of polymer science.

    Building the Next Generation of Chemical Supply

    Nobody in manufacturing gets every batch right, every time. We invite constant questioning and keep records stretching back decades, so new team members draw from a deep well of lessons learned. Customers are encouraged to visit our plant floor, see our process in action, and hold us to their highest requirements. By basing improvements on what actually happens, not what just looks good in a quarterly report, we lay the groundwork for lasting trust in our products.

    Adiponitrile may look like just a line on an order sheet, but for us, every container represents a hundred small choices: in safety, in process control, in the way we handle customer feedback – choices that add up to reliability where it counts. That’s why companies who depend on strong, fault-free polymers and demanding process lines put their confidence in our team. As future markets call for new materials and even higher standards, experience in the details will remain our best asset.

    From process chemistry to logistics, from the plant floor to the R&D bench, our commitment stays the same: deliver Adiponitrile that works every time, because that’s what both our customers and their customers deserve.